A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article，once mentioned of 37366-09-9, Formula: C12H12Cl4Ru2
The reactions of PhSe-, PhS- and Se2- with N-{2-(chloroethyl)}pyrrolidine result in N-{2-(phenylseleno)ethyl}pyrrolidine (L1), N-{2-(phenylthio)ethyl}pyrrolidine (L2), and bis{2-pyrrolidene-N-yl)ethyl selenide (L3), respectively, which have been explored as ligands. The complexes [PdCl2(L1/L2)] (1/7), [PtCl2(L1/L2)] (2/8), [RuCl(eta6-C6H6)(L1/L2)][PF6] (3/9), [RuCl(eta6-p-cymene)(L1/L2)][PF6] (4/10), [RuCl(eta6-p-cymene)(NH3)2][PF6] (5) and [Ru(eta6-p-cymene)(L1)(CH3CN)][PF6]2·CH3CN (6) have been synthesized. The L1-L3 and complexes were found to give characteristic NMR (Proton, Carbon-13 and Se-77). The crystal structures of complexes 1, 3-6, 9 and 10 have been solved. The Pd-Se and Ru-Se bond lengths have been found to be 2.353(2) and 2.480(11)/2.4918(9)/2.4770(5) A?, respectively. The complexes 1 and 7 have been explored for catalytic Heck and Suzuki-Miyaura coupling reactions. The value of TON has been found up to 85 000 with the advantage of catalyst’s stability under ambient conditions. The efficiency of 1 is marginally better than 7. The Ru-complexes 3 and 9 are good for catalytic oxidation of primary and secondary alcohols in CH2Cl2 in the presence of N-methylmorpholine-N-oxide (NMO). The TON value varies between 8.0 × 104 and 9.7 × 104 for this oxidation. The 3 is somewhat more efficient catalyst than 9.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Product Details of 37366-09-9, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 37366-09-9, in my other articles.
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI