In an article, published in an article, once mentioned the application of 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer,molecular formula is C12H12Cl4Ru2, is a conventional compound. this article was the specific content is as follows.SDS of cas: 37366-09-9
Ruthenium complexes [(eta5-C5H5) Ru(PPh3)(kappa2-paa)]PF6 (paa = pyridine-2-carbaldehyde azine) and [(eta5-C5H 5)Ru(kappa1-dppm)-(kappa2-paa)]BF 4 [dppm = bis(diphenylphosphanyl)methane] have been employed as a synthon in the synthesis of homo/hetero bi-/trimetallic complexes. It is the uncoordinated N,N-donor site on paa in complex [(eta5-C 5H5)Ru(PPh3)-(kappa2-paa)]PF 6, and N,N-donor site on paa and pendant phosphorus in [(eta5-C5H5)Ru(kappa1-dppm) (kappa2-paa)]BF4 that allows for their incorporation into bi-/trimetallic systems. The resulting complexes have been characterized by analytical, spectral and electrochemical studies. Molecular structures of homobimetallic complex [(PPh3)(theta5-C 5H5)Ru(mu-paa)Ru(theta6-C 10H14)Cl](PF6)2 and hetero-bimetallic complex [(PPh3)(theta5-C 5H5)-Ru(mu-paa)Rh(theta5-C 5Me5)Cl](PF6)2 have been authenticated crystallographically. Complexes exhibit absorptions throughout the visible region and complicated electrochemical behaviour. Metal-based Ru II/RuIII oxidations in the bimetallic complexes do not vary as in the trimetallic complexes. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI