The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article，once mentioned of 32993-05-8, Application In Synthesis of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Ruthenium allenylidene complexes with carbon-rich polyaromatic moieties have been synthesized by using [RuCl(eta5-C5H5)(PPh3)2] (eta5-C5H5 = cyclopentadienyl) as a precursor and the propargyl alcohols 10-ethynyl-10-hydroxyanthracen-9-one (ACO), 13-ethynyl-13-hydroxypentacen-6-one (PCO), 1-phenyl-1-(pyren-1-yl)prop-2-yn-1-ol (PyrPh), 9-ethynyl-9H-fluoren-9-ol (FN) and 6-ethynyl-6H-benzo[cd]pyren-6-ol (BPyr) as ligands. The resulting cationic allenylidene complexes, [Ru(eta5-C5H5)(CC(AO))(PPh3)2]PF6 (1), [Ru(eta5-C5H5)(CC(PCO))(PPh3)2]PF6 (2), [Ru(eta5-C5H5)(CC(PyrPh))(PPh3)2]PF6 (3), [Ru(eta5-C5H5)(CC(FN))(PPh3)2]PF6 (4), and [Ru(eta5-C5H5)(CC(BPyr))(PPh3)2]PF6 (5) show interesting intermolecular pi-interactions in the solid-state structure as well as solution state complexation with pyrene (documented by Job’s plots experiments). CV data indicate possible Ru(ii)/Ru(iii) oxidation, as well as the potential reduction of the carbon-rich allenylidene moiety.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Quality Control of: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), you can also check out more blogs about32993-05-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI