Application of 32993-05-8. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II). In a document type is Article, introducing its new discovery.
Complexes of the types cis-L2PtCl2 (L = PPh3, 1/2 dppe) and cpRu(PPh3)2Cl react with 1-alkyne-1-thiolates to give the products trans-(Ph3P)2Pt(S-C<*>C-Ph)2 (5), dppePt(S-C<*>C-Ph)2 (6) and CpRu(PPh3)2(S-C<*>C-Ph) (7), respectively.CpRu(PPh3)(CO)(S-C<*>C-Ph) (8) is formed by reaction of 7 in an atmosphere of CO.The 2-propene-1-thiolato complexes dppePt(S-CH2-CH=CH2)2 (9), CpFe(CO)2(S-CH2-CH=CH2) (12) and CpFe(PPh3)(CO)(S-CH2-CH=CH2) (13) are obtained from dppePtCl2, CpFe(CO)2I, CpFe(PPh3)(CO)I and lithium or sodium 2-propene-1-thiolate.The complexes are characterized by IR and (1)H, (13)C and (31)P NMR spectroscopy.Keywords: 1-Alkyne-1-thiolato, 2-Propene-1-thiolato, Metal Complexes
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI