Some scientific research about Dichloro(benzene)ruthenium(II) dimer

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Related Products of 37366-09-9. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer. In a document type is Article, introducing its new discovery.

Dehydrogenating complexation of borolenes with carbonyls (Ru3(CO)12, Os3(CO)12), Wilkinson’s catalyst (RhCl(PPh3)3) and related compounds (RuCl2(PPh3)3, RuHCl(PPh3)3, OsCl2(PPh3)3), and (eta6-arene)ruthenium complexes (Ru(eta-C6H6)(eta4-C6H8), 2, 2) leads to the (eta5-borole)metal complexes of Ru, Os, and Rh.Inter alia, the preparation of the complexes Ru(CO)3(eta5-C4H4BR) (R = Ph, OMe, Me), Os(CO)3L (L = eta5-C4H4BPh), MHClL(PPh3)2 (M = Ru, Os), RhClL(PPh3)2, and RuL(eta-C6R6) (R = H, Me) is described.The structures of RuHClL(PPh3)2 and RhClL(PPh3)2 have been determined by X-ray diffraction analysis.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI