Related Products of 32993-05-8, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a patent, introducing its new discovery.
The complex [RuCl(eta5-C5H5){PPh2(2-MeC 6H4)}2] (1), unlike the triphenylphosphine analog [RuCl(eta5-C5H5)(PPh3) 2], reacts under mild conditions with CO, N2CPh2 and HC?CPh to give the neutral carbonyl, carbene and vinylidene derivatives [RuCl(eta5-C5H5)(L){PPh 2(2-MeC6H4)}] (L = CO 2, CPh2 5, C=CHPh 6), respectively, via displacement of one phosphine ligand. The vinylidene complex 6 promptly reacts with benzylamine affording the aminocarbene [RuCl(eta5-C5H5){=C(NHCH 2Ph)CH2Ph} {PPh2(2-MeC6H4)}] (7). Moreover, the cyclometalated derivative [Ru(eta5-C5H5){PPh2(2-CH 2C6H4)}{PPh2(2-MeC6H 4)}] (4) has been obtained from the methyl complex [RuMe(eta5-C5H5){PPh2(2-MeC 6H4)}2] (3) by intramolecular C-H bond cleavage and methane elimination. Complex 1, whose X-ray structure analysis is also reported, has been found to catalyze alkyne coupling reactions.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI