A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article，once mentioned of 37366-09-9, Application In Synthesis of Dichloro(benzene)ruthenium(II) dimer
Two new aminophosphines – furfuryl-(N-dicyclohexylphosphino)amine, [Cy 2PNHCH2-C4H3O] (1) and thiophene-(N-dicyclohexylphosphino)amine, [Cy2PNHCH 2-C4H3S] (2) – were prepared by the reaction of chlorodicyclohexylphosphine with furfurylamine and thiophene-2-methylamine. Reaction of the aminophosphines with [Ru(eta6-p-cymene)(mu-Cl)Cl] 2 or [Ru(eta6-benzene)(mu-Cl)Cl]2 gave corresponding complexes [Ru(Cy2PNHCH2-C4H 3O)(eta6-p-cymene)Cl2] (1a), [Ru(Cy 2PNHCH2-C4H3O)(eta6- benzene)Cl2] (1b), [Ru(Cy2PNHCH2-C 4H3S)(eta6-p-cymene)Cl2] (2a) and [Ru(Cy2PNHCH2-C4H3S) (eta6-benzene)Cl2] (2b), respectively, which are suitable catalyst precursors for the transfer hydrogenation of ketones. In particular, [Ru(Cy2PNHCH2-C4H 3S)(eta6-benzene)Cl2] acts as a good catalyst, giving the corresponding alcohols in 98-99% yield in 30 min at 82 C (up to time of flight ? 588 h-1).
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Application In Synthesis of Dichloro(benzene)ruthenium(II) dimer, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 37366-09-9, in my other articles.
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI