Synthetic Route of 37366-09-9, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a patent, introducing its new discovery.
A series of salts composed of the coordinatively unsaturated ruthenium beta-diketiminato cation [(eta6C6H6) Ru((ArNCMe)2CH)]+ (Ar = 2,6-dimethylphenyl) and different anions, i.e., OTf- (1), BF4- (2), PF 6- (3), BPh4- (4), and BArF – (B((3,5-CF3)2C6H3) 4-) (5), have been prepared and characterized. The solid state structures of 1, 2, and 5 have also been established using single-crystal X-ray diffraction. Both solution and solid state data reveal the presence of anion-cation interactions, the extent of which depends on the nature of the anion,.which have been further rationalized via computed charge density profiles using DFT energy optimized models. The catalytic activity of 1-5 in the hydrogenation of styrene was found to be highly dependent on the nature of the counteranion, as inferred from investigations based on high-pressure solution NMR, pulsed gradient spin-echo (PGSE) NMR diffusion, and Overhauser NMR spectroscopy. A good correlation between catalytic activity and the extent and nature of ion pairing was found, and the structure of the active catalytic species is proposed.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI