Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Safety of Dichloro(benzene)ruthenium(II) dimer. In my other articles, you can also check out more blogs about 37366-09-9
A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article,once mentioned of 37366-09-9, Safety of Dichloro(benzene)ruthenium(II) dimer
New piano-stool ruthenium(II) complexes, (2+), (1+), (1+), (1+) and (1+) have been isolated as their hexafluorophosphate salts by bridge-cleavage reactions of <2> in methanol with the potentially tri- and bi-dentate nitrogen-containing ligands <2-(2-pyridyl)ethyl>(2-pyridylmethyl)methylamine (L1), 2,6-bis(pyrazol-1-ylmethyl)pyridine (L2) and its tetramethyl-substituted derivative (L3), 2-(pyrazol-1-ylmethyl)pyridine (L4) and its dimethyl derivative (L5).The structures of these compounds in MeCN solution have been elucidated by 1H NMR spectroscopy.The complex 2 has been characterized by single-crystal X-ray crystallography: triclinic, space group P<*> (no. 2), a = 7.790(3), b = 10.039(3), c = 16.679(5) Angstroem, alpha = 88.31(2), beta = 83.15(3), gamma = 77.19(3) deg and Z = 2.The structure has been refined to an R factor of 0.063 based on 5330 observed reflections.Average Ru-C and Ru-N (two types) bond lengts are 2.202(6) and 2.114(5) and 2.170(5) Angstroem respectively.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Safety of Dichloro(benzene)ruthenium(II) dimer. In my other articles, you can also check out more blogs about 37366-09-9
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI