Application of 32993-05-8, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a patent, introducing its new discovery.
This article details the preparation and spectroscopic characterization of a focused library of new 18-electron ruthenocenyl complexes incorporating pentasubstituted Cp ester [C5(CO2R)5] – (for R = Me, Et, n-Pr, n-Bu, 2-Pr, 3-Pent, phenyl, and n-thiopropyl), carboxylic acid [C5(CO2H)5] -, and carboxylate ligands [C5(CO2H) 4(CO2)]2-. Each complex has been characterized using Fourier transform IR and NMR spectroscopy and electrospray mass spectrometry, with single-crystal X-ray structural determinations reported for four complexes: [Ru(eta5-C5H4(C 5(CO2CH3)5)(eta5-C 5(CO2CH3)5)], K[Ru(eta 5-C5H5)(eta5-C5(CO 2H)4(CO2))].H2O, [Ru(eta5-C5H5)(eta5-C 5(CO2H)5)]·2H2O, and [Ru(eta5-C5H5)(eta5-C 5(CO2C6H5)5)]. Complexes were also evaluated for in vitro cytotoxic activity against a diverse panel of tumorigenic cell lines and a normal human cell line.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI