Reference of 246047-72-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium. In a document type is Article, introducing its new discovery.
A new Grubbs-Hoveyda-Blechert alkene metathesis catalyst, in which the benzylidene ligand has been coordinated to a highly electron-withdrawing tricarbonylchromium moiety, is presented. The structure of the complex provides evidence for a so far unreported attractive interaction between the benzylidene hydrogen atom and one of the mesityl substituents at the Arduengo carbene ligand. Screening of the catalytic properties shows that the activity of the new catalyst in ring-closing, enyne, cross, and homo metathesis of alkenes is comparable and in some cases better than that of known catalysts.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI