Reference of 10049-08-8, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.10049-08-8, Name is Ruthenium(III) chloride, molecular formula is Cl3Ru. In a patent, introducing its new discovery.
The synthesis of the ligand 4-methyl-4?-vinyl-2,2?-bipyridine is discussed. Methods previously reported presented problems in terms of yield and purity of a precursor. Traces of starting material (4,4?-dimethyl-2,2?-bipyridine) contaminated the product and this contaminant carried through to the synthesis of 4-methyl-4?-vinyl-2,2?-bipyridine. Thus, upon complexation to form ruthenium tris (4-methyl-4?-vinyl-2,2?-bipyridine) bis (hexafluorophosphate), the bis-, mono- and non-vinyl complexes were also present. Electropolymerisation of ruthenium tris (4-methyl-4?-vinyl-2,2?-bipyridine) bis (hexafluorophosphate) to produce a high quality polymer film requires the maximum number of vinyl ligands per molecule of complex. The relative percentages of complexes within the mixture can be calculated using proton NMR. This method is based upon the integration values of the vinyl resonances of the tris- and bis-compounds. However, a simple mathematical model has been developed that can predict the percentage composition of the mixture prior to complexation by taking into account the purity of 4-methyl-4?-vinyl-2,2?-bipyridine. The novel syntheses of 4-(2-hydroxypropyl)-4?-methyl-2,2?-bipyridine, 4-methyl-4?-(E-prop-2-enyl)-2,2?-bipyridine and ruthenium tris (4-methyl-4?-(E-prop-2-enyl-2,2?-bipyridine) bis (hexafluorophosphate) are also described. Full spectral data for all compounds, together with novel data for ruthenium tris (4-methyl-4?-vinyl-2,2?-bipyridine) bis (hexafluorophosphate), are reported.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI