37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, name: Dichloro(benzene)ruthenium(II) dimer
The complex [(eta5-MeC5H4)Ru(DPVP)2(CH3 CN)]PF6 (4) (DPVP = Ph2PCH=CH2) loses CH3CN under vacuum to produce the phosphaallyl complex [(eta5-MeC5H4)Ru(eta1-DPVP)( eta3-DPVP)]PF6 (6) and reacts with Me3SiC?CH and PhC?CH in CH2Cl2-CH3OH solutions to form the methoxymethylcarbene [(eta5-MeC5H4)(DPVP)2Ru=C(OCH 3)(CH3)]PF6 (7) and the carbonyl complex [(eta5-MeC5H4)Ru(DPVP)2(CO)]PF 6 (8), respectively. In contrast [(eta5-MeC5H4)Ru(DPVP)(CO)(CH3CN)] PF6 (15) does not lose CH3CN to form a phosphaallyl complex. The structures of the complexes described herein have been deduced from elemental analyses, infrared spectroscopy, 1H, 13C{1H}, 1H NOE, where appropriate by 31P{1H} NMR spectroscopy and in eight cases by X-ray crystallography.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.name: Dichloro(benzene)ruthenium(II) dimer. In my other articles, you can also check out more blogs about 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI