32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 32993-05-8, Quality Control of: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
The reaction of (eta5-C5H5)Ru<(C6H5)3P>2Cl with Co(CO)4- leads to a mixture of metal containing products.One of these products (eta5-C5H5)Ru<(C6H5)3P>2(CO)5Co*THF was isolated in pure form and its structure determined.The complex crystallizes in space group P21/n with a 15.015(1), b 18.543(3), c 16.984(2) Angstroem beta 110.75(1), V=4422 Angstroem3 and Z=4.The structure has been refined to R=0.072, Rw 0.073 for 3643 observed reflections.The molecule consist of a (eta5-C6H5)Ru<(C6H5)3P>2(CO)+ cation or Cr(CO)4- anion and a THF molecule of crystallization.The cation has a typical “piano-stool” structure and the Co(CO)4- anion has a nearly ideal tetrahedral configuration.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Quality Control of: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II). In my other articles, you can also check out more blogs about 32993-05-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI