Archives for Chemistry Experiments of (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium

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The synthesis and characterization of a cis-dichloro sulfur chelated olefin metathesis catalyst is presented. The catalyst was extremely stable at room temperature in solution under ambient conditions and was shown to exhibit a thermoswitchable behavior for ring-closing olefin metathesis of diethyl diallylmalonate, being active at 80C and inactive at room temperature.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI