New explortion of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.Recommanded Product: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

A detailed kinetic investigation of the reaction of with cycloheptatriene, cyclohepta-1,3-diene, cyclooctatetraene, penta-1,4-diene, cycloocta-1,5-diene and dimethyl maleate, has been carried out spectrophotometrically in CH2Cl2 at 10 deg C.It is shown that the major mechanism is via dissociation of PPh3 to give which then reacts with the olefin.There is also a second mechanism involving direct attack of the olefin on .

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI