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Figure Presented Radically complex: Well-defined mononuclear RuI and OsI complexes (see scheme) have metalloradical character, as indicated by EPR spectroscopy and DFT calculations. The RuI and OsI metalloradicals exhibit both one-electron and two-electron redox reactivity. The latter process affords unusual imido complexes with substantial radical character on the {ArN} moiety.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI