A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article，once mentioned of 37366-09-9, Safety of Dichloro(benzene)ruthenium(II) dimer
Abstract: The new water soluble chiral Ru(II)-benzene complexes of the type [RuCl 2(eta6-C 6H 6) L] were obtained from the reactions between [RuCl2(eta6-C6H6)]2 and the chiral aroylthiourea ligands (L) derived from unprotected D/L-alanine and characterized. The solid-state structure of representative complexes was confirmed by single crystal X-ray diffraction technique. The Ru(II)-benzene complexes catalyzed the asymmetric transfer hydrogenation (ATH) of aromatic ketones to their enantiopure secondary alcohols. The reactions were carried out in the presence of formic acid?triethylamine mixture in water, and the product alcohols were obtained with excellent conversions (up to 99%) and enantiomeric excesses (up to 99%). The scope of the catalytic system was extended to various aromatic ketones. The catalytic activity of the present water-soluble Ru-benzene complexes toward enantioselective reduction of ketones was considerably higher than that of p-cymene analogues in water. Graphical Abstract: The water-soluble chiral Ru(II)-benzene complexes were produced from the reactions between [RuCl2(eta6-C6H6)]2 and the chiral aroylthiourea ligands derived from unprotected D/L-alanine. The catalytic activity of the Ru(II)-benzene complexes toward enantioselective reduction of ketones was found to be good in water medium.[Figure not available: see fulltext.].
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Safety of Dichloro(benzene)ruthenium(II) dimer. In my other articles, you can also check out more blogs about 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI