Electric Literature of 37366-09-9, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a patent, introducing its new discovery.
New series of half-sandwich ruthenium(II) complexes supported by a group of bidentate pyridylpyrazole and pyridylimidazole ligands [(eta6-C6H6)Ru(L2)Cl][PF6] (1), [(eta6-C6H6)Ru(HL3)Cl][PF6] (2), [(eta6-C6H6)Ru(L4)Cl][PF6] (3), and [(eta6-C6H6)Ru(HL5)Cl][PF6] (4) [L2, 2-[3-(4-chlorophenyl)pyrazol-1-ylmethyl]pyridine; HL3, 3-(2-pyridyl)pyrazole; L4, 1-benzyl-[3-(2?-pyridyl)]pyrazole; HL5, 2-(1-imidazol-2-yl)pyridine] are reported. The molecular structures of 1-4 both in the solid state by X-ray crystallography and in solution using 1H NMR spectroscopy have been elucidated. Further, the crystal packing in the complexes is stabilized by C-H?X (X = Cl and pi), N-H?Cl, and pi-pi interactions.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI