Electric Literature of 20759-14-2. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 20759-14-2, Name is Ruthenium(III) chloride hydrate
The crystal structures of three complexes of dicarboxy-2,2′-bipyridyl ligands, 5,5′-dicarboxy-2,2′-bipyridyl (1) and 4,4′-dicarboxy-2,2′-bipyridyl (2) are reported. [Rh(1H)3] shows two interpenetrating, homochiral rhombohedral networks linked by short carboxylate-carboxylic acid hydrogen bonds, in which each complex acts as a node for six hydrogen bonds. [Ru(1H2)(1H)2] forms only four such hydrogen bonds, leading to the formation of heterochiral chains held together by stacking between bipyridyls. [Co(2H)3] can in principle form six hydrogen bonds, but in practice forms only four in a layer structure where stacking interactions are important. This is attributed to differences in molecular shape. Copyright 2004 The Royal Society of Chemistry
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI