Reference of 14564-35-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 14564-35-3, Name is Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II). In a document type is Article, introducing its new discovery.
The hydrosilylation of allyl chloride with timethoxysilane has been examined in the presence of several homogenous complex catalysts. Iridium and ruthenium complexes exhibit higher selectivities in the reaction to give 3-chloropropyltimethoxysilane. Other complexes usually give propylene and/or tetramethoxysilane as side products in large quantities. The Ru3(CO)12-catalyzed reactions effected at lower temperature or by using a large excess of trimethoxysilane relative to allyl chloride give the chloropropylsilane in good yields.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI