Related Products of 37366-09-9. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer. In a document type is Article, introducing its new discovery.
The complexes CpRu(eta5-Th)+ (1), where Th is thiophene or a methyl-substituted thiophene, react with hydrides such as H2Al(OCH2CH2OMe)2- to give (eq.3) the C-S cleaved butadiene-thiolate product 3.Subsequent reactions of 3 are shown: <*> This scheme is not intended to indicate that all reactions were performed on the thiophene complex; many were carried out using the methyl-substituted thiophene analogs.Structures of complexes of the types 6 and 9 were established by X-ray diffraction studies.Possible mechanisms for reaction 3 are considered, and stereochemistries of all complexes are established by 1 H NMR spectrometry.Implications for the mechanism of the catalytic hydrodesulfurization of thiophene are discussed.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI