Reference of 37366-09-9. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer. In a document type is Article, introducing its new discovery.
Highly conjugated perinones were evaluated as proligands with [Ru(eta6-arene)Cl2]2 precursors (arene = p-cymene or benzene). None of them, except itaco-perinone (IP) bearing one exocyclic methylene group, were able to form coordination compounds. Expected eta1-coordination through the lone pair of the nitrogen or oxygen atoms of the perinone did not occur. Instead a deprotonation reaction involving the exocyclic methylene was observed and the corresponding [Ru(eta6-arene)(eta3-IP)Cl] complex was isolated in moderate yields. Mechanistic studies revealed that the base-promoted isomerization of itaco-perinone to citraco-perinone prevented higher yields in the synthesis of the allylic complexes. Additionally, it was observed that IP can dimerize through the exocyclic methylene group, indicating high reactivity of this carbon?carbon double bond. Electronic absorption and emission properties of the perinones and organometallic compounds were studied.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI