Electric Literature of 92361-49-4. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 92361-49-4, Name is Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II)
A method for regioselective solid-phase synthesis of disubstituted peptidoisoxazoles is reported. Improved conditions for the synthesis of 3,5-disubstituted isoxazoles (mimicking s-trans peptide bond) without metal catalysts were implemented. New conditions enabling the synthesis of 3,4-disubstituted isoxazoles (mimicking s-cis peptide bond) using ruthenium catalysts were developed. This study provides a means for the regioselective preparation of new libraries of peptidomimetic molecules containing an isoxazole moiety within the backbone.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI