Top Picks: new discover of Dichloro(benzene)ruthenium(II) dimer

The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 37366-09-9 is helpful to your research., name: Dichloro(benzene)ruthenium(II) dimer

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article,once mentioned of 37366-09-9, name: Dichloro(benzene)ruthenium(II) dimer

The reactions of 2-(pyridine-2-ylmethylsulfanyl)benzoic acid (L) with [(5-Cp/6-benzene)MCl(-Cl)]2, (benzene, M = Ru; Cp, M = Rh, Ir) at room temperature followed by treatment with NH 4PF6 result in a new class of water-soluble half-sandwich complexes [(5Cp/6-benzene)M(L)Cl][PF6] (13, respectively, for M = Ru, Rh, Ir). Their characteristic HR-MS and 1H and 13C{1H} NMR spectra have been found. The single-crystal structures of 13 have been established with X-ray crystallography. The Ru S, Rh S, and Ir S bond lengths are 2.4079(6), 2.3989(10), and 2.3637(14), respectively. Complexes 13 have been found to be efficient for catalytic transfer hydrogenation (TH) of carbonyl compounds in water with glycerol as a hydrogen donor. Glycerol has been explored for TH in water for the first time. The efficiency in water of other hydrogen sources, viz. HCOOH, citric acid, ascorbic acid, and 2-propanol, is less and/or is pH dependent. Catalysis with glycerol as a hydrogen source is pH independent and appears to be homogeneous. Higher reactivity for the Rh complex in comparison to the Ru and Ir species has been observed. DFT calculations are generally consistent with the experimental values of bond lengths and angles and catalytic reactivity order.

The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 37366-09-9 is helpful to your research., name: Dichloro(benzene)ruthenium(II) dimer

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI