37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, Quality Control of: Dichloro(benzene)ruthenium(II) dimer
The heteronuclear complex [(Me2PhP)3Cl2Re?N-RuCl2(C 6H6)] (1) is obtained by the reaction of [ReNCl2(PMe2Ph)3] with [RuCl2(C6H6)]2 in C6H5CN in form of red crystals with the composition 1·C6H5CN crystallizing in the monoclinic space group P21/c with a =1149.77(8), b = 3085.9(3), c = 1172.1(1) pm, beta = 104.766(9) and Z = 4. In the dinuclear complex the complex fragment [RuCl2(C6H6)] is connected by an asymmetric nitrido bridge with the nitrido complex [ReNCl2(PMe2Ph)3]. The nitrido bridge is characterised by a bond angle Re-N-Ru of 170.6(3) and distances Re-N = 170.2(5) and Ru-N = 199.0(5) pm. The reaction of [ReNCl2(PMe2Ph)3] with [RhCl(COD)]2 in benzo-nitrile yields orange crystals of [(Me2PhP)3Cl2Re?N-RhCl(COD)] (2) with the space group P21/c and a = 1522.3(2), b = 1274.85(4), c = 1921.2(2) pm, beta = 106.759(7) and Z = 4. The monovalent Rh atom exhibits a square planar coordination with the two pi-bonds of the cycloocta-1,5-diene occupying cis positions. The distances in the almost linear nitrido bridge (Re-N-Rh = 174.8(4)) are Re-N = 172.2(6) pm and Rh-N = 195.6(6) pm.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Quality Control of: Dichloro(benzene)ruthenium(II) dimer. In my other articles, you can also check out more blogs about 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI