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Related Products of 32993-05-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Reactions between <(L2 = 1,2-bis(diphenylphosphino)ethane (dppe) and 1,2-bis(phenylphosphino)methane (dppm)>, and 1-ethynylpyrene , in the presence of NH4PF6, NaBF4 or NaBPh4, have given the corresponding cationic eta’-vinylidene complexes.These cations are readily deprotonated to give the corresponding eta’-ethynyl complexes.They have been characterised on the basis of elemental analyses and spectroscopic studies.The cationic and neutral products have been further treated with methanol and higher alcohols and the resulting products characterised.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI