Do you like my blog? If you like, you can also browse other articles about this kind. Application In Synthesis of Ruthenium(III) chloride. Thanks for taking the time to read the blog about 10049-08-8
In an article, published in an article, once mentioned the application of 10049-08-8, Name is Ruthenium(III) chloride,molecular formula is Cl3Ru, is a conventional compound. this article was the specific content is as follows.Application In Synthesis of Ruthenium(III) chloride
This paper describes the systematic preparation and characterization of new families of triple-decker sandwich complexes incorporating formal cyclo-Et2C2B3H3(4-) bridging ligands, including the first species of this class containing second- or third-row transition metals.Complexes of general formula (L)M(Et2C2B3H3)M'(L) (M = Ru, Os; M’ = Co, Ru; L = cymene , Cp, or C5Me5) were obtained in stepwise fashion via (1) synthesis of closo-(L)M(Et2C2B4H4) metallacarboranes, (2) “decapitation” (apex BH removal) of these complexes to give nido-(L)M(Et2C2B3H5), (3) bridge deprotonation to form the corresponding mono- or dianion, and (4) reaction of the anion with an arene metal halide to generate the desired triple-decker compound.In addition, the cobalt-iron triple-decker CpCo(Et2C2B3H3)FeCp was prepared via treatment of (eta6-C8H10)Fe(Et2C2B3H4)(1-) with Na(1+)Cp(1-) and CoCl2 followed by air oxidation.The reaction of (CO)3RuCl2 with (C5Me5)Co(Et2C2B3H3)(2-) gave the “pseudo-triple-decker” complex (C5Me5)Co(Et2C2B3H3)Ru(CO)3.The triple-deckers, especially those containing osmium, are susceptible to chlorination by RuCl3, OsCl3, or dichloromethane, forming exclusively the 4-chloro derivatives.All of the characterized triple-decker complexes are air-stable crystalline solids (except for the osmium-ruthenium species, which are air sensitive) and have been structurally characterized from their (11)B and (1)H NMR, infrared, visible-UV, and unit- and high-resolution mass spectra, further supported by X-ray crystallographic analyses of (cymene)Ru(Et2C2B3H3)Ru(cymene) (10) and CpCo(Et2C2B3H3)Ru(cymene) (11a).Crystal data for 10: mol wt 561.13; space group PI; Z = 2; a = 10.409(3), b = 11.268(5), c = 12.002(4) Angstroem; alpha = 96.16(3), beta = 99.49(2), gamma = 106.69(3) deg; V = 1312(2) Angstroem3; R = 0.043 for 4777 reflections having F02 > 3?(F02).Crystal data for 11a: mol wt 476.92; space group P21/c; Z = 4; a = 8.808(6), b = 17.708(8), c = 14.194(8) Angstroem; beta = 103.50(4) deg; V = 2153(4) Angstroem3; R = 0.058 for 3289 reflections having F02 > 3?(F02).
Do you like my blog? If you like, you can also browse other articles about this kind. Application In Synthesis of Ruthenium(III) chloride. Thanks for taking the time to read the blog about 10049-08-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI