Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 10049-08-8, Name is Ruthenium(III) chloride, Application In Synthesis of Ruthenium(III) chloride.
Polymerization of methyl methacrylate (MMA) with triethanolamine (TEA) and carbon tetrachloride has been investigated in the presence of RuCl3 and in dimethyl sulphoxide (DMSO) medium by employing a dilatometric technique at 60C. The rate of polymerization (R(p)) of MMA has been found to be proportional to [MMA], [TEA]( 1/2 ), [CCl4]( 1/2 ) and {k(I) + k(II)[RuCl3]( 1/2 )} where k(I) and k(II) are rate constants for uncatalysed and catalysed polymerization respectively. The rate of polymerization has been inhibited by hydroquinone, suggesting a free radical mechanism. The kinetic data indicate the possible participation of the charge transfer complex formed between {TEA-Ru(III)} and CCl4 during the polymerization of MMA. In the absence of either TEA or CCl4, no polymerization of MMA has been observed under the present experimental conditions.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Application In Synthesis of Ruthenium(III) chloride. In my other articles, you can also check out more blogs about 10049-08-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI