A new application about Dichloro(benzene)ruthenium(II) dimer

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9

A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article，once mentioned of 37366-09-9, Computed Properties of C12H12Cl4Ru2

First examples of heteroleptic arene ruthenium complexes containing dipyrrin ligands with the general formulations [(eta6-arene)RuCI(L) ] [(arene = C6H6, C10H14; L = 5-(4-cyanophenyl)-dipyrromethene, cydpm; 5-(4-nitrophenyl)-dipyrromethene, ndpm and 5-(4-benzyloxyphenyl)-dipyrromethene, bdpm] have been synthesized. The complexes [eta6 -C10H14)RuCI(L)] (L = ndpm and cydpm) reacted with NaN3 and NH4SCN to afford neutral mononuclear complexes [(eta6-C10H14)Ru(N 3)(L)] and [eta6 -C10H14)Ru(SCN) (L)]. Their reactions with EPh3 (E = P, As) and exobidentate ditopic P-P and N-N donor ligands, namely, bis-(diphenylphosphino)methane (dppm) and 4,4?-bipyridine (bpy) in the presence of AgSO3CF3 afforded cationic mono- and binuclear complexes [(eta6 -C 10-H14)Ru(L)(EPh3)]SO3CF 3, [{(eta6-C10H14)Ru(L)} 2(mu-dppm)](SO3CF3)2, and [{(eta6-C10H14)Ru(L)}2(mu-bpy)] (S03-CF3)2, respectively. The reaction products have been characterized by analytical and spectral studies. Molecular structures of the representative complexes [eta6-C 10H14)RuCI(cydpm)], [(eta6-C 6H6)RuCI(cydpm)], [eta6-C10H 14)RuCI-(ndpm)], [(eta6-C10H 14)Ru(N3)(ndpm)], and [eta6-C 10H14)Ru(PPh3)(ndpm)]SO3CF 3 have been determined crystal-lographically. Redox behavior of the complexes has been investigated by electrochemical studies. Emission spectral studies at room temperature suggested that the complexes under study are non-emissive.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9

Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI