In an article, published in an article, once mentioned the application of 20759-14-2, Name is Ruthenium(III) chloride hydrate,molecular formula is Cl3H2ORu, is a conventional compound. this article was the specific content is as follows.Computed Properties of Cl3H2ORu
We herein describe the synthesis and characterization of a series of homoleptic, Ru(II) complexes bearing peripheral carboxylic acid functionality based upon the novel ligand 4?-(4-carboxyphenyl)-4,4?-di-(tert-butyl)tpy (L1), as well as 4?-(4-carboxyphenyl)tpy (L2) and 4?-(carboxy)tpy (L3) (where tpy = 2,2?: 6?,2?-terpyridine). Inspection of the metal-based oxidations (E1/2 = 1.22-1.42 V) indicates an anodic shift (?0.2 V) for (L3)2Ru2+ (3b) (E1/2 = 1.40 V) relative to (L2)2Ru2+ (2b) (E1/2 = 1.22 V). The metal-based oxidation (E1/2 = 1.22 V) and ligand-based reductions (E1/2 = -1.25 to -1.52 V) of (L1)2Ru2+ (1) are essentially invariant relative to those of the structural analogue 2b (PF6)2, which suggests no significant electronic effect caused by the tert-butyl groups. This is supported by invariance in the metal-to-ligand charge transfer bands in both the electronic absorption (494-489 nm) and emission spectra (654-652 nm). However, contrary to 2b, complex 1 is both very soluble and exhibits a highly porous solid-state structure with internal cavity dimensions of 15 A × 14 A due to the preclusion of inter-annular interactions by the bulky tert-butyl substituents.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI