Related Products of 10049-08-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 10049-08-8, Cl3Ru. A document type is Article, introducing its new discovery.
The oxidation of methyl glycol, ethyl glycol, diethylene glycol and tetraethylene glycol by alkaline hexacyanoferrate(III) using ruthenium(III) chloride as a homogeneous catalyst, was studied at constant ionic strength.The reaction velocity shows direct proportionality with respect to ruthenium(III) chloride concentrations.The reaction rate shows reverse proportionality with respect to hydroxide ion concentration.The reaction follows first order kinetics with respect to low concentrations of the organic substrate, but at high concentrations of the latter the reaction becomes independent with respect to the organic substrate concentrations.These data suggest the formation of an activated complex between the glycol anion and ruthenium(III) species.The complex, thus formed, slowly breaks up into the intermediate products and ruthenium(III) hydride species which in turn is further oxidized by taking more of hexacyanoferrate(III) in the subsequent steps.
If you are hungry for even more, make sure to check my other article about 10049-08-8. Related Products of 10049-08-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI