Final Thoughts on Chemistry for (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium

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Reference of 246047-72-3, An article , which mentions 246047-72-3, molecular formula is C46H65Cl2N2PRu. The compound – (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium played an important role in people’s production and life.

A new synthetic route to optically active unsaturated gamma- and delta-lactones has been demonstrated via asymmetric allylic carboxylation with a planar-chiral Cp?Ru catalyst and ring-closing metathesis reaction with a Grubbs II catalyst, and successfully applied to the enantioselective synthesis of (R)-(-)-massoialactone. The Royal Society of Chemistry 2012.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI