Awesome and Easy Science Experiments about Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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Reference of 32993-05-8, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a patent, introducing its new discovery.

The 1-alkyne-1-thiolates R-CC-Sli <1: R = SiMe3, 3: (eta5-C5H4)Fe(eta5-C5H5)> react with (Ph3P)2PtCl2 and CpRu(PPh3)2Cl to give the complexes trans-(Ph3P)2Pt(S-CC-SiMe3)2 (4a).CpRu(PPh3)2S-CC-SiMe3) (4b), and cis-(Ph3P)2Pt(S-CC-eta5-C5H4)Fe(eta5-C5H5)>2 (5).The Pt(II)bis(acetylide) complex cis-(Ph3P)2Pt2 (6a) was isolated after chromatography of 5.The trans-configurated compound 6b is obtained by the reaction of Fe(eta5-C5H5) with (Ph3P)2PtCl2.The complexes are characterized by IR, 1H-, 13C-, and 31P-NMR spectroscopy, FAB mass spectrometry and X-ray diffraction (6a). – Key Words: 1-Alkyne-1-thiolato ligands / Bis(acetylide) complexes / Ferrocene derivatives / Ruthenium complexes / Platinum complexes

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI