Reference of 172222-30-9. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 172222-30-9, Name is Benzylidenebis(tricyclohexylphosphine)dichlororuthenium
A new stereocenter is formed by ring-rearrangement metathesis (RRM), which has now been extended to diastereoselective processes. Selectivities are catalyst- and substrate-dependent. In these conversions yielding carbo- and heterocycles, d.r. values of up to 14:1 were obtained. For example, cyclooctadiene 1 was converted into piperideine 2 at room temperature and with high diastereoselectivity (Ts = toluene-4-sulfonyl). (Chemical Equation Presented).
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI