Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 10049-08-8, Cl3Ru. A document type is Article, introducing its new discovery., Quality Control of: Ruthenium(III) chloride
Complexes of bis(thiophene 2-carboxaldehyde)-o-tolidin (o-tolidin = 4,4′-diamino-3,3′-dimethylbiphenyl) with Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Ru(III), Rh(III), Pd(II), Ir(IV), Pt(IV) and Au(III) have been prepared.The complexes have been characterised on the basis of analytical, conductance, IR spectral, electronic spectral and magnetic moment data.IR spectra show that the ligand acts as a tetradentate molecule.Molar conductance data in DMF indicate that Rh(III) and Ir(IV) complexes are 1:2 electrolytes; and Pt(IV) complex is 1:4 electrolyte.The ESR spectrum of Cu(II) complex shows a compressed rhombic symmetry with a distorted trigonal-bipyramidal geometry probably with dZ2 ground state.The magnetic moments of the complexes show that all the complexes except Co(II) complex are of high-spin type.The Co(II) complex shows a spin paired-spin free equilibrium.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI