Extended knowledge of Dichloro(benzene)ruthenium(II) dimer

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In an article, published in an article, once mentioned the application of 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer,molecular formula is C12H12Cl4Ru2, is a conventional compound. this article was the specific content is as follows.Recommanded Product: Dichloro(benzene)ruthenium(II) dimer

The complex cations [Ru(C7H16N2)(C 10H14)Cl]+, [Ru(C7H 16N2)(C6H6)Cl]+, [Ru(C9H18N2)(C6H6)Cl] +, [Ru(C9H18N2)(C10H 14)Cl]+ and [Ru(C14H16N 2)(C10H14)Cl]+ have been synthesised from the reaction between the ruthenium-arene complexes [with C 6H6 (benzene) or C10H14 (p-cymene)] and the respective chiral diamines [C7H16N2 = (S)-(-)-2-aminomethyl-1-ethylpyrrolidine, C9H18N 2 = (S)-(+)-2-(pyrrolidinylmethyl)-pyrrolidine, or C 14H16N2 = (1R,2R)-(+)-1,2- diphenylethylenediamine], isolated and characterised as chloride salts using single-crystal X-ray diffraction. All complexes were fully characterised by elemental analysis, mass spectrometry, 13C and 1H NMR, and also found to exhibit catalytic activity in the transfer hydrogenation of acetophenone to 1-phenylethanol at 50C (enantiomeric excesses range from ca. 25% to 60%, and conversions from ca. 30% to 50%).

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI