Archives for Chemistry Experiments of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 32993-05-8 is helpful to your research., Related Products of 32993-05-8

Related Products of 32993-05-8, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article,once mentioned of 32993-05-8

Bis(2-hydroxy-1-naphthyl)methane reacts with chlorodiphenylphosphine to afford the bis(phosphinite), Ph2P{(-OC10H6)(mu-CH2)(C10 H6O-)}PPh2 (1) in good yield. The bis(phosphinite) 1 reacts with elemental sulfur or selenium to give the corresponding disulfide or diselenide; the structure of the selenium derivative, Ph2P(Se){(-OC10H6)(mu-CH2)(C1 0H6O-)}P(Se)Ph2 (3) is confirmed by X-ray crystal structure analysis. Treatment of the ligand 1 with platinum metal derivatives results in the formation of ten-membered chelate complexes with the ligand showing an eta2-mode of coordination. The elucidation of the structures of the products is based on NMR (1H and 31P) spectroscopic data. Molecular structures of [CpRuCl{eta2-Ph2P{(-OC10H6)(mu-C H2)(C10H6O-)}PPh2-kappaP,kappaP} ] (4) and [PtCl2{eta2-Ph2P{(-OC10H6 )(mu-CH2)(C10H6O-)}PPh2- kappaP, kappaP}] (7) are determined by single crystal X-ray studies.

The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 32993-05-8 is helpful to your research., Related Products of 32993-05-8

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI