In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.Recommanded Product: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Reactions of carbon-rich bispropargyl alcohols with two equivalents of the ruthenium precursor [RuCl(eta5-C5H5)(PPh3)2] and NH4[PF6], respectively, result in dinuclear ruthenium bisallenylidene complexes [Ru(eta5-C5H5)(PPh3)2([dbnd]C[dbnd]C[dbnd])(AC)([dbnd]C[dbnd]C[dbnd])(PPh3)2(eta5-C5H5)Ru](PF6)2(7), [Ru(eta5-C5H5)(PPh3)2([dbnd]C[dbnd]C[dbnd])(PC)([dbnd]C[dbnd]C[dbnd])(PPh3)2(eta5-C5H5)Ru](PF6)2(9), [Ru(eta5-C5H5)(PPh3)2([dbnd]C[dbnd]C[dbnd])(BAN)([dbnd]C[dbnd]C[dbnd])(PPh3)2(eta5-C5H5)Ru](PF6)2(10), and [Ru(eta5-C5H5)(PPh3)2([dbnd]C[dbnd]C[dbnd])(IndFN)([dbnd]C[dbnd]C[dbnd])(PPh3)2(eta5-C5H5)Ru](PF6)2(11) (polyaromatic moieties: AC = anthracene, PC = pentacene, BAN = bianthracene, IndFN = indenofluorene). These complexes show distinct spectroscopic and electronic properties, which could be investigated by cyclic voltammetry and UV/Vis/NIR spectroscopic measurements.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI