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Application of 32993-05-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery.
The compound Me2C(PPh2)2 (2,2-dppp) reacted with 0.5 equivalent of to afford monomeric 1.Metathesis with LiBr afforded 2.With 0.25 equivalent of the rigid, square-planar Cl 3 was formed.These results are in sharp contrast to the chemistry seen with H2C(PPh2)2 and H(Me)C(PPh2)2.With 0.5 equivalent of , 2,2-dppp reacted to give brown-orange trans- 4a.In solution this is in equilibrium with a green five-co-ordinate species Cl 4b, the first such complex to be observed with a four-membered chelating diphosphine.With , 2,2-dppp reacted to form 5.Although its rhodium(I) chemistry suggests that 2,2-dppp favours chelation rather than bridging modes of co-ordination, when 5 was treated with 0.5 equivalent of it readily formed <(eta-C5H5)Ru(mu-CO)2(mu-2,2-dppp)RhCl2>(Ru-Ru) 6.The structures of 4-6 have been determined by X-ray diffraction.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI