The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article,once mentioned of 32993-05-8, HPLC of Formula: C41H35ClP2Ru
The complex [(eta5-C5H5)Ru(PPh 3)2Cl] (1) reacts with several arylazoimidazole (RaaiR?) ligands, viz., 2-(phenylazo)imidazole (Phai-H), 1-methyl-2-(phenylazo)imidazole (Phai-Me), 1-ethyl-2-(phenylazo)imidazole (Phai-Et), 2-(tolylazo)imidazole (Tai-H), 1-methyl-2-(tolylazo)imidazole (Tai-Me) and 1-ethyl-2-(tolylazo)imidazole (Tai-Et), gave complexes of the type [(eta5-C5H5)Ru(PPh3)(RaaiR?) ]+ {where R, R? = H (2), R = H, R? = CH3 (3), R = H, R? = C2H5 (4), R = CH3, R? = H (5), R, R? = CH3 (6), R = CH3, R? = C 2H5 (7)}. The complex [(eta5-C 9H7)Ru(PPh3)2(CH3CN)] + (8) undergoes reactions with a series of N,N-donor azo ligands in methanol yielding complexes of the type [(eta5-C9H 7) Ru(PPh3)(RaaiR?)]+ {where R, R? = H (9), R = H, R? = CH3 (10), R = CH3, R? = H (11), R = CH3, R? = C2H5 (12)}, respectively. These complexes were characterized by FT IR and FT NMR spectroscopy as well as by analytical data. The molecular structure of the complex [(eta5-C5H5)Ru(PPh 3)(C6H5-NN-C3H3N 2)]+ (2) was established by single crystal X-ray diffraction study.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.HPLC of Formula: C41H35ClP2Ru, you can also check out more blogs about32993-05-8
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI