Synthetic Route of 32993-05-8. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II). In a document type is Article, introducing its new discovery.
Further MS(FD) investigations of CpRu(eta6-C6H5)BPh3 have revealed under increased heating current of the field ion emitter the next set of signals centered at m/e 652.To account for this phenomenon, the formation of the dinuclear <(CpRu(eta6-C6H5))2BPh2>+ cation containing two Cp rings, is proposed.The rearrangement of CpRu(eta6-C6H5)BPh3 into a new ion-pair with <(CpRu(eta6-C6H5))2BPh2>+ cation is also observed in high-boiling point media, such as ethylene glycol.The ion-pair with the tetraphenylborate anion (yield 35percent), has been isolated from the reaction.The duration of refluxing was extremely long (100-700 hours).The new ion-pair with BPh4- anion is stable and its MS(FD) spectrum shows only the set of signals centered at m/e 652.The mechanism for the synthesis CpRu(eta6-C6H5)BPh3 and its novel complex cation and their MS(FD) investigations are presented.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI