Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Recommanded Product: 14564-35-3. In my other articles, you can also check out more blogs about 14564-35-3
14564-35-3, Name is Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), molecular formula is C38H34Cl2O2P2Ru, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 14564-35-3, Recommanded Product: 14564-35-3
The synthesis of a series of ruthenium(II) complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane L of type (+) containing H, O2CCF3, CO, PPh3, dppe <1,2-bis(diphenylphosphino)ethane> or 2,6-Me2C6H3N<*>C as auxiliary ligands are described where X = Y = CO, Z = Cl 1; X, Y = dppe, Z = Cl 2; X, Y = dppe, Z = H 3; X = CO, Y = PPh3, Z = 4; X = Y = 2,6-Me2C6H3N<*>C, Z = O2CCF3 5.All complexes were characterized by spectroscopic methods.The crystal structures of 1 and 4 as PF6(-) salts have been determined.The two CO groups in complex 1 are in cis-fashion with a OC-Ru-CO angle of 90.1(3) deg and the Ru-C distances are 1.850(6) and 1.893(6) Angstroem.Complex 4 features one of the few ruthenium complexes containing three different piano-stool ligands, namely, CO, PPh3 and H.The measured Ru-CO and Ru-H distances in 4 are 1.785(9) and 1.54(9) Angstroem respectively.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Recommanded Product: 14564-35-3. In my other articles, you can also check out more blogs about 14564-35-3
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI