Reference of 246047-72-3, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 246047-72-3, C46H65Cl2N2PRu. A document type is Article, introducing its new discovery.
A latent Ru olefin metathesis catalyst bearing a chelating ligand with an azoxybenzene fragment was obtained and characterized. The complex was inactive in the ring closing metathesis (RCM) reaction of a standard test diene: diethyl diallylmalonate at room temperature but can be subsequently activated by elevated temperature (up to 100 C). The lack of activity of this azoxy catalyst in RCM of dienes containing terminal C-C double bonds at room temperature and high activity in ring opening metathesis polymerization (ROMP) of bicyclo [2.2.1]hept-2-ene (norbornene, NBE) permitted the ROMP of the challenging monomer: 5-vinyl-2-norbornene yielding soluble polymers with cyclopentenylenevinylene chains with vinyl pendant groups.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI