If you are hungry for even more, make sure to check my other article about 32993-05-8. Electric Literature of 32993-05-8
Electric Literature of 32993-05-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
The molecular structures (1) and (2) have been determined.In 1, strain about the RuPCC chelate ring is accommodated largely by contraction of the intra-ring angles about the relevant atoms.In 2 there are similar contractions, together with marked lengthening of the Ru-C(sp2) bond (to 2.149(5) Angstroem) and of the C-C bond (1.534(7) Angstroem) from the vinyl alpha-carbon to the CHPPh2 group of the chelating tertiary phosphine; the latter bond is 0.11 Angstroem shorter than that in the iron analogue.Crystal data: 1 (as 0.5CH2Cl2 solvate): triclinic, space group P1-, a 8.409(2), b 19.055(5), c 21.921(9) Angstroem, alpha 94.10(3), beta 97.02(2), gamma 99.92(2) deg, U 3418.6 Angstroem3, Z=4; 2007 data (I>/=2.5?(I)) were refined to R=0.047, Rw=0.051; 2: triclinic, space group P1-, a 12.141(1), b 14.004(1), c 11.333(1) Angstroem, alpha 112.19(1), beta 101.15(1), gamma 69.01(1) deg, U 1662.0 Angstroem3, Z=2, 3788 data (I>/=2.5?(I)) were refined to R=0.047, Rw=0.050.
If you are hungry for even more, make sure to check my other article about 32993-05-8. Electric Literature of 32993-05-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI