The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article,once mentioned of 32993-05-8, Formula: C41H35ClP2Ru
An intramolecular Diels-Alder (IMDA) reaction was observed at room temperature between an allyl group and a chloroanthracenyl group that were both bonded to the vinylidene ligand of the cationic ruthenium complex [Ru]=C=C(CH2CH=CH2)CH(CH2CH=CH 2)(C14H8Cl)+ (6; [Ru] = Cp(PPh 3)3Ru). The vinylidene ligand functions as a mediator to bring the allyl and the chloroanthracenyl groups in proximity for the reaction to take place. For the two allyl groups in 6, only the one at Cbeta underwent the reaction. In the analogous triethylphosphine complex 6 , more electron-donating triethylphosphine ligands lower the rate of the IMDA reaction. For this IMDA reaction in several vinylidene complexes, each with a nonchlorinated anthracenyl ligand, the rate of the reaction is accelerated by the presence of an unsaturated functional group at Cgamma of the vinylidene ligand, particularly by a terminal alkynyl substituent. The solid-state structures of two IMDA reaction products have been determined by single-crystal X-ray diffraction analysis.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Formula: C41H35ClP2Ru, you can also check out more blogs about32993-05-8
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI