Application of 301224-40-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 301224-40-8, C31H38Cl2N2ORu. A document type is Article, introducing its new discovery.
For the first time, a deconjugative electrophilic fluorodesilylation reaction was accomplished. gamma-Silyl butenamides were treated with Selectfluor to provide alpha-fluoro-beta,gamma-unsaturated amides. Other sources of electrophilic fluorine were not efficient or gave protodesilylated side products. The electrophilic fluorodesilylation reaction was followed by a ruthenium-catalyzed cross-metathesis of the resulting functionalized allylic fluoride. The fluorodesilylation/cross-metathesis sequence is ideal for the synthesis of fluoro analogues of symbioramide.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI