In an article, published in an article, once mentioned the application of 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II),molecular formula is C20H16Cl2N4Ru, is a conventional compound. this article was the specific content is as follows.Product Details of 15746-57-3
Metal-coordinated “gamma-lactam-capped” and “imide-capped” 1,10-phenanthroline ligands are reported. Whereas the imide-functionalized ligand 1,10-phenanthroline-5,6-carboximide could not be obtained as a free ligand, probably due to its extremely low solubility, we developed a protocol to first introduce the more soluble 1,10-phenanthrolino[5, 6-c]pyrrole in the ligand sphere of cyclometalated iridium(III) complexes, followed by the oxidation of the pyrrole moiety to a maleimide utilizing a peroxybenzoic acid. The hydrogen bond donor-acceptor properties of the new ligands should make them suitable building blocks for the design of metal-based protein binders. Furthermore, we unexpectedly found that bis-cyclometalated iridium(III) complexes coordinated to 1,10-phenanthroline-5,6-carboximide display luminescence properties that are dependent on the protonation state of the maleimide NH group. It can be envisioned to exploit this behavior for the real-time monitoring of hydrogen bonding interactions in biological systems.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI