37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, SDS of cas: 37366-09-9
The catalytic hydrogenation of various benzene derivatives was studied, using (eta6-C6H6)2Ru2Cl4 in aqueous solution as the catalyst precursor. Under biphasic conditions, the corresponding cyclohexane derivatives are obtained with catalytic turnover rates which vary, depending on the substrate, from 20 to 2000 cycles per h. After a catalytic run, the aqueous solution contains the two tetranuclear cations [(eta6-C6H6)4Ru4H4]2+ and [(eta6-C6H6)4Ru4H6]2+ which are known to catalyse the hydrogenation of aromatic compounds, but the activity of which is considerably lower than that of the (eta6-C6H6)2Ru2Cl4 precursor. An intermediate, presumably the more active species, was detected by 1H-NMR spectroscopy under catalytic conditions and identified as the trinuclear cluster cation [Ru3(eta6-C6H6)3(mu2-Cl)(mu3-O)(mu2-H)2]+.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.SDS of cas: 37366-09-9. In my other articles, you can also check out more blogs about 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI