In an article, published in an article, once mentioned the application of 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer,molecular formula is C12H12Cl4Ru2, is a conventional compound. this article was the specific content is as follows.Formula: C12H12Cl4Ru2
The invention discloses based on a four-methyl modifier of the skeleton of the phosphine compounds and intermediates thereof and preparation method and use thereof. The states phosphine ligand compound is having the general formula I or formula II the structure shown as the compound or the compound of the enantiomer, racemate or non-enantiomer. The phosphine to cheap and easy to obtain four methyl spiral dihydro yinyin diphenol as a raw material, by the general formula III as a key intermediate in the preparation route to obtain. The invention has developed a novel phosphine, can be used for catalytic organic reaction, in particular can be used as a chiral phosphine widely used for including the asymmetric hydrogenation and not to the aqueous system such as allylic alkylation in many asymmetric catalytic reaction, has the economic and practical and industrial application prospect. (by machine translation)
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI